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PHỤ LỤC
Phụ lục 1: Bảng PL1. Ma trận thiết kế hoàn chỉnh cho các thí nghiệm và hiệu suất Hydrochar vỏ hạt cà phê thu được từ quá trình carbon hóa thủy nhiệt (%).
Nhiệt độ | Thời gian | Vỏ hạt cà phê /Nước | Hiệu suất Hydrochar vỏ hạt cà phê | |
1 | -1 | -1 | -1 | 71,77 |
2 | 1 | -1 | -1 | 49,29 |
3 | -1 | 1 | -1 | 57,26 |
4 | 1 | 1 | -1 | 42,95 |
5 | -1 | -1 | 1 | 71,43 |
6 | 1 | -1 | 1 | 45,61 |
7 | -1 | 1 | 1 | 57,30 |
8 | 1 | 1 | 1 | 39,65 |
9 | -1 | 0 | 0 | 59,71 |
10 | 1 | 0 | 0 | 49,76 |
11 | 0 | -1 | 0 | 57,71 |
12 | 0 | 1 | 0 | 52,65 |
13 | 0 | 0 | -1 | 54,05 |
14 | 0 | 0 | 1 | 53,60 |
15 | 0 | 0 | 0 | 54,85 |
16 | 0 | 0 | 0 | 54,82 |
17 | 0 | 0 | 0 | 54,83 |
18 | 0 | 0 | 0 | 54,82 |
19 | 0 | 0 | 0 | 54,81 |
20 | 0 | 0 | 0 | 54,86 |
Có thể bạn quan tâm!
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Nghiên cứu than hóa phụ phẩm nông nghiệp vỏ hạt cà phê, lõi bắp bằng phương pháp carbon hóa thủy nhiệt, ứng dụng làm vật liệu hấp phụ và xúc tác - 18 -
Nghiên cứu than hóa phụ phẩm nông nghiệp vỏ hạt cà phê, lõi bắp bằng phương pháp carbon hóa thủy nhiệt, ứng dụng làm vật liệu hấp phụ và xúc tác - 19 -
Nghiên cứu than hóa phụ phẩm nông nghiệp vỏ hạt cà phê, lõi bắp bằng phương pháp carbon hóa thủy nhiệt, ứng dụng làm vật liệu hấp phụ và xúc tác - 20 -
Nghiên cứu than hóa phụ phẩm nông nghiệp vỏ hạt cà phê, lõi bắp bằng phương pháp carbon hóa thủy nhiệt, ứng dụng làm vật liệu hấp phụ và xúc tác - 22
Xem toàn bộ 180 trang tài liệu này.
Phụ lục 2: Bảng PL 2. Ma trận thiết kế hoàn chỉnh cho các thí nghiệm và hiệu suất Hydrochar lõi bắp thu được từ quá trình carbon hóa thủy nhiệt (%).
Nhiệt độ | Thời gian | Lõi bắp /Nước | Hiệu suất Hydrochar lõi bắp | |
1 | –1 | –1 | –1 | 78,449 |
2 | 1 | –1 | –1 | 48,768 |
3 | –1 | 1 | –1 | 48,363 |
4 | 1 | 1 | –1 | 43,233 |
5 | –1 | –1 | 1 | 82,920 |
6 | 1 | –1 | 1 | 46,204 |
7 | –1 | 1 | 1 | 62,115 |
8 | 1 | 1 | 1 | 44,162 |
9 | –1 | 0 | 0 | 57,898 |
10 | 1 | 0 | 0 | 50,541 |
11 | 0 | –1 | 0 | 61,662 |
12 | 0 | 1 | 0 | 52,311 |
13 | 0 | 0 | –1 | 50,099 |
14 | 0 | 0 | 1 | 53,331 |
15 | 0 | 0 | 0 | 52,149 |
16 | 0 | 0 | 0 | 53,380 |
17 | 0 | 0 | 0 | 52,594 |
18 | 0 | 0 | 0 | 52,500 |
19 | 0 | 0 | 0 | 51,709 |
20 | 0 | 0 | 0 | 52,027 |
Phụ lục 3: Bảng PL 3. Hệ số hồi quy ước lượng mối tương quan của các yếu tố ảnh hưởng trong quá trình HTC vỏ hạt cà phê.
Hệ số | Sai số chuẩn | Giá trị p | Khoảng tin cậy | |
Hằng số | 54,7306 | 0,1313 | 1,213x10-16 | 0,3106 |
Nhiệt độ | -3,3692 | 0,1960 | 5,546x10-7 | 0,4635 |
Thời gian | -1,8716 | 0,1960 | 2,902x10-5 | 0,4635 |
Tỉ lệ sinh khối: nước | -0,2471 | 0,1960 | 0,2477 | 0,4635 |
(Nhiệt độ)2 | 0,0463 | 0,1212 | 0,7134 | 0,2868 |
(Thời gian)2 | 0,1736 | 0,1212 | 0,1954 | 0,2868 |
(Tỉ lệ sinh khối: nước)2 | -0,2137 | 0,1212 | 0,1213 | 0,2868 |
Nhiệt độ x Thời gian | 0,8992 | 0,0711 | 4,469x10-6 | 0,1681 |
Nhiệt độ x Tỉ lệ sinh khối: nước | -0,3829 | 0,0711 | 0,0010 | 0,1681 |
Thời gian x Tỉ lệ sinh khối: nước | -0,0161 | 0,0711 | 0,8265 | 0,1681 |
(Nhiệt độ)2 x Thời gian | -1,1095 | 0,1153 | 2,764x10-5 | 0,2727 |
(Nhiệt độ)2xTỉ lệ sinh khối: nước | -0,1643 | 0,1153 | 0,1972 | 0,2727 |
Nhiệt độ x (Thời gian)2 | -1,9286 | 0,1153 | 6,700x10-7 | 0,2727 |
Phụ lục 4: Bảng PL 4. Hệ số hồi quy ước lượng mối tương quan của các yếu tố ảnh hưởng trong quá trình HTC lõi bắp.
Hệ số | Sai số chuẩn | Giá trị p | Khoảng tin cậy | |
Hằng số | 52,9741 | 0,5990 | 6,23 x 10–12 | 1,4165 |
Nhiệt độ | – 3,6387 | 0,8939 | 0,0047 | 2,1137 |
Thời gian | – 2,7086 | 0,8939 | 0,0191 | 2,1137 |
Tỉ lệ sinh khối: nước | 0,8106 | 0,8939 | 0,3946 | 2,1137 |
(Nhiệt độ)2 | 0,5885 | 0,5530 | 0,3225 | 1,3077 |
(Thời gian)2 | 1,3574 | 0,5530 | 0,0438 | 1,3077 |
(Tỉ lệ sinh khối: nước)2 | – 0,1074 | 0,5530 | 0,8514 | 1,3077 |
Nhiệt độ x Thời gian | 2,8616 | 0,3242 | 4,85 x 10–5 | 0,7667 |
Nhiệt độ x Tỉ lệ sinh khối: nước | – 1,3119 | 0,3242 | 0,0048 | 0,7667 |
Thời gian x Tỉ lệ sinh khối: nước | 0,8439 | 0,3242 | 0,0352 | 0,7667 |
(Nhiệt độ)2 x Thời gian | – 1,4396 | 0,5260 | 0,0290 | 1,2438 |
(Nhiệt độ)2x Tỉ lệ sinh khối: nước | 0,3968 | 0,5260 | 0,4752 | 1,2438 |
Nhiệt độ x (Thời gian)2 | – 2,3429 | 0,5260 | 0,0029 | 1,2438 |
Phụ lục 5: Bảng PL 5. Thông số phương trình đẳng nhiệt hấp phụ xanh methylen của các mẫu than sinh học hoạt hóa.
Vật liệu | Mô hình đẳng nhiệt Langmuir | Mô hình đẳng nhiệt Freundlich | q thực nghiệm | ||||||
Qm (mg/g) | KL (L/mg) | RL | R2 | KF | n | R2 | qexp (mg/g) | ||
1 | CHhydro | 357,14 | 0,6667 | 0,0030 - 0,0291 | 1,000 | 129,60 | 4,10 | 0,661 | 357,38 ± 0,349 |
2 | CChydro | 400,00 | 0,6579 | 0,0149 - 0,0295 | 0,998 | 153,39 | 4,43 | 0,536 | 395,05 ± 0,931 |
3 | CHmagnet | 270,27 | 0,0629 | 0,0002 - 0,2382 | 0,994 | 44,79 | 2,94 | 0,966 | 263,21 ± 0,972 |
4 | CCmagnet | 285,71 | 0,0582 | 0,0332 - 0,2540 | 0,994 | 44,21 | 2,85 | 0,977 | 271,27 ± 0,985 |
5 | CHimpreg | 316,46 | 0,7822 | 0,0026 - 0,0249 | 1,000 | 124,19 | 4,86 | 0,604 | 314,05 ± 0,978 |
6 | CCimpreg | 370,37 | 0,6585 | 0,0030 - 0,0295 | 1,000 | 126,33 | 3,65 | 0,676 | 369,76 ± 0,894 |
7 | CHactiv | 500,00 | 1,2500 | 0,0016 - 0,0157 | 0,998 | 233,92 | 3,75 | 0,638 | 475,43 ± 0,578 |
8 | CCactiv | 500,00 | 0,9091 | 0,0022 - 0,0215 | 0,995 | 189,54 | 2,25 | 0,746 | 481,58 ± 0,921 |
9 | CHbiochar | 312,50 | 1,6842 | 0,0012 - 0,0117 | 1,000 | 134,00 | 4,86 | 0,718 | 315,53 ± 0,879 |
10 | CCbiochar | 322,58 | 0,7561 | 0,0026 - 0,0258 | 1,000 | 119,59 | 4,31 | 0,623 | 322,00 ± 0,953 |