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P. Results of Treatment of Organic Substances in Leachate by Perozone with the Effect of Ph in 60 Minute Reaction Time


Experiment

Before processing

After coagulation

Manganese ore content (mg/l)

0

100

200

300

400

500

600

700

Experiment 3

4,263

3,580

772

632

575

544

536

488

489

488

2. COD (mg/l)

Experiment 1

6.630

5,197

3,226

3,091

2,698

2,385

2,082

1,947

1,902

1,902

Experiment 2

5.242

4.211

2,688

2,643

2,306

2,037

1,858

1,623

1,623

1,588

Experiment 3

5,690

4,570

2,778

2,643

2,464

2,295

2,026

1,937

1,882

1,837

3. TOC (mg/l)

Experiment 1

2,145

1,873

1,384

1,354

1,290

1,279

1,193

1,154

1,136

1.135

Experiment 2

1,788

1,530

1.201

1,140

1,026

986

940

911

907

906

Experiment 3

1,934

1,749

1,324

1,240

1,120

1.114

1.108

1,100

1,089

1,096

4. BOD5 ( mg/l)

Experiment 1

2,332

1,870

1,318

1,360

1,160

1,070

934

868

843

821

Experiment 2

1,734

1,372

1,086

1,224

1,012

915

824

752

760

753

Experiment 3

1,950

1,606

1,166

1.124

1,150

1,056

940

874

871

863

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P. Results of Treatment of Organic Substances in Leachate by Perozone with the Effect of Ph in 60 Minute Reaction Time


Table 5p. Results of treating organic substances in leachate with Perozon with the influence of pH in a reaction time of 60 minutes


Experiment

Before processing

After coagulation

pH

5

6

7

8

9

10

1. Color (Pt-Co)

Experiment 1

2,821

1,995

569

572

556

531

513

524

Experiment 2

2,790

2,100

643

649

632

616

638

649

Experiment 3

2,665

2,047

528

516

520

517

484

495

2. COD (mg/l)

Experiment 1

2,178

1,672

1,298

1,232

1,210

1,100

1.122

1,166

Experiment 2

2,966

2,307

1,936

1,895

1,854

1,524

1,607

1,730

Experiment 3

3,390

2,712

2,134

2,147

2,034

1,695

1,695

1,808

3. TOC (mg/l)

Experiment 1

1,060

780

695

678

660

643

633

650

Experiment 2

1,022

768

721

680

657

613

592

590

Experiment 3

1306

995

802

775

730

688

693

724

4. BOD5 ( mg/l)

Experiment 1

642

487

428

433

412

454

458

443

Experiment 2

928

742

650

605

640

560

572

596

Experiment 3

994

820

750

766

728

670

656

710


Table 6p. Results of treating organic substances in leachate with Perozon under the influence of H 2 O 2 at pH 8 and reaction time of 60 minutes


Experiment

Before processing

After coagulation

H 2 O 2 content (mg/l)

500

750

1000

1250

1500

1750

2000

2250

2500

1. Color (Pt-Co)

Experiment 1

2.125

1,806

616

605

592

528

480

448

438

450

486

Experiment 2

2,050

1,533

534

534

534

450

432

426

420

456

510

Experiment 3

2,475

2,058

638

594

561

498

486

462

450

456

516

2. COD (mg/l)

Experiment 1

3,388

2,750

2,134

2,068

2.002

1,980

1,914

1,848

1,738

1,870

1,936

Experiment 2

3,074

2,442

1,788

1,744

1,722

1,657

1,613

1,504

1,504

1,570

1,679

Experiment 3

3,717

2,868

2.141

2.020

1,939

1,858

1,818

1,818

1,778

1,939

2,060

3. TOC (mg/l)

Experiment 1

1,096

906

832

814

766

740

730

714

698

718

771

Experiment 2

864

743

665

628

606

585

576

588

578

608

627

Experiment 3

1,296

1,043

892

865

864

855

836

825

825

848

855

4. BOD5 ( mg/l)

Experiment 1

874

762

712

695

673

651

644

640

648

647

683

Experiment 2

950

806

624

593

588

572

568

518

536

542

587

Experiment 3

1,036

890

726

707

684

694

680

650

655

647

691


Table 7p. Results of treating organic substances in leachate with Perozon with the influence of reaction time at pH 8 and H 2 O 2 (2,000 mg/l)


Experiment

Before processing

After coagulation

Reaction time (min)

40

60

80

100

120

140

1. Color (Pt-Co)

Experiment 1

3,050

2,800

2,100

979

748

572

462

396

Experiment 2

2,375

2,100

1,225

649

426

267

210

213

Experiment 3

2,475

2,025

1,302

572

222

174

165

138

2. COD (mg/l)

Experiment 1

3,379

2,638

1,984

1,679

1,330

1,243

1,221

1,221

Experiment 2

2,904

2,200

1,716

1,496

1,100

1,056

1,056

1,034

Experiment 3

3.019

2,176

1,732

1,288

1,021

977

977

932

3. TOC (mg/l)

Experiment 1

1,021

822

634

588

572

510

498

465

Experiment 2

992

803

648

587

579

515

482

488

Experiment 3

956

724

567

544

478

468

465

436

4. BOD5 ( mg/l)


Experiment

Before processing

After coagulation

Reaction time (min)

40

60

80

100

120

140

Experiment 1

1.126

906

725

648

565

528

542

538

Experiment 2

807

667

583

532

460

468

466

468

Experiment 3

733

601

520

504

416

413

428

422


Table 8p. Results of treating organic substances in leachate with Perozon/ceramic buffer at pH 8 and reaction time 80 minutes


Experiment

Before processing

After coagulation

Specific surface of ceramic pad (m 2 /m 3 )

0

356

539

728

1. Color (Pt-Co)

Experiment 1

2.125

1,680

462

444

444

410

Experiment 2

2,300

1,650

576

528

420

414

Experiment 3

2,425

1,806

456

354

360

246

2. COD (mg/l)

Experiment 1

2,746

2,142

1,352

1,331

1,269

1.123

Experiment 2

2,870

2,246

1,414

1,352

1,290

1,082

Experiment 3

3.154

2,333

1.555

1,512

1,382

1,166

3. TOC (mg/l)

Experiment 1

955

825

547

528

471

464

Experiment 2

1,010

890

632

626

565

541

Experiment 3

979

858

517

523

492

449

4. BOD5 ( mg/l)

Experiment 1

825

649

606

605

591

539

Experiment 2

866

702

629

617

614

565

Experiment 3

870

710

716

705

702

598


Table 9p. Results of treating organic substances in leachate with Perozon/manganese ore at pH 8 and reaction time 80 minutes


Experiment

Before processing

After coagulation

Manganese ore content (mg/l)

0

100

200

300

400

500

600

700

1. Color (Pt-Co)

Experiment 1

5,082

4,177

657

607

601

562

479

477

474

453

Experiment 2

6,068

5.360

751

714

683

666

600

589

585

585

Experiment 3

4,263

3,580

634

626

605

483

387

374

372

372

2. COD (mg/l)

Experiment 1

6.630

5,197

2,733

2,464

2,195

2.016

1,813

1,654

1,554

1,610


Experiment

Before processing

After coagulation

Manganese ore content (mg/l)

0

100

200

300

400

500

600

700

Experiment 2

5.242

4.211

2.016

1,926

1,613

1,568

1,444

1,286

1,286

1,286

Experiment 3

5,690

4,570

2,285

1,971

1,747

1,613

1,444

1,295

1,258

1,275

3. TOC (mg/l)

Experiment 1

2,145

1,873

1,236

1,236

1,183

1,079

1,044

1,042

993

999

Experiment 2

1,788

1,530

1,063

960

937

940

908

902

875

850

Experiment 3

1,934

1,749

1,263

1,178

1,086

975

953

889

886

884

4. BOD5 ( mg/l)

Experiment 1

2,332

1,870

1,216

1,082

963

927

801

759

775

763

Experiment 2

1,734

1,372

956

946

826

790

683

618

621

602

Experiment 3

1,950

1,606

946

816

778

727

681

651

648

656


Appendix 10 : RESULTS OF REGRESSION AND CORRELATION ANALYSIS

1. Regression and correlation analysis program for the treatment of organic substances in leachate using Ozone and Perozone

CHARACTER H*20

MULREG01.for PROGRAM (11/2014) SWIMMING RECRUITMENT CONFERENCE

STANDARDIZED METHOD OF VARIABLES OF Van Huu Tap - INSTITUTE OF TECHNOLOGY PROCESSING EFFECTIVENESS (%) ACCORDING TO:

Color (Y1) COD (Y2) TOC (Y3)

DEPENDS ON FACTORS:

1. CASE OF OZONE TREATMENT

pH (X1), reaction time (X2), specific surface area (X3), manganese content (X4)

2. CASE OF HANDLING BY PEROZONE

pH (X1), reaction time (X2), H2O2 content (X3), specific gravity (X4), manganese content (X5)

DIMENSION X(100,10),Y(100),YTT(100),DEL(100),SS(100),X0(100,10),


*Y0(100),XTB(10),SX(10),XX0(10,10),XY0(10),RS(10),A(100),B(10),

*BB(10)

WRITE(*,*) 'FILE SO LIEU?' READ(*,1) H

1 FORMAT(A) OPEN(1,FILE=H,STATUS='UNKNOWN') WRITE(*,*) 'FILE KET PASS?' READ(*,1) H OPEN(3,FILE=H,STATUS='UNKNOWN') READ (1,*) N,M

READ (1,*) ((X(I,J),J=1,M),Y(I),I=1,N) WRITE (3,*) 'SO LIKELY:' WRITE (3, 2) N, M

2 FORMAT(/5X,'N=',I3,3X,'M=',I2) WRITE (3,*)

WRITE (3,*)' X(I,J) & Y(I) ' IF(M.EQ.4) GOTO 111

WRITE (3,3) (I,(X(I,J),J=1,M),Y(I),I=1,N)

3 FORMAT(I3,2X,5F7.1,2X,F6.2)

GOTO 222

111 WRITE(3,112) (I,(X(I,J),J=1,M),Y(I),I=1,N)

112 FORMAT(I3,2X,4F7.1,2X,F6.2)

222 CONTINUE SUM=0.

DO 31 I=1,N

31 SUM=SUM+Y(I) YTB=SUM/N

SUM=0.

DO 32 I=1,N

32 SUM=SUM+(Y(I)-YTB)*(Y(I)-YTB)


SY=SQRT(SUM/(N-1)) DO 33 I=1,N

33 Y0(I)=(Y(I)-YTB)/SY

DO 35 J=1,M SUM=0.

DO 34 I=1,N

34 SUM=SUM+X(I,J) 35 XTB(J)=SUM/N

DO 37 J=1,M SUM=0.

DO 36 I=1,N

36 SUM=SUM+(X(I,J)-XTB(J))*(X(I,J)-XTB(J))

37 SX(J)=SQRT(SUM/(N-1))

DO 38 J=1,M

DO 38 I=1,N

38 X0(I,J)=(X(I,J)-XTB(J))/SX(J) WRITE(3,*)

WRITE(3,*)

WRITE(3,*) 'KET THROUGH TOTAL:' WRITE(3,*)

DO 5 J=1,M

DO 5 K=1,M SUM=0.

DO 4 I=1,N

4 SUM=SUM+X0(I,J)*X0(I,K) 5 XX0(J,K)=SUM

DO 7 J=1,M SUM=0. DO 6 I=1,N

6 SUM=SUM+X0(I,J)*Y0(I)


7 XY0(J)=SUM

DO 77 J=1,M

77 RS(J)=XY0(J)/(N-1)

WRITE(3,*)' HE IS SO VIEW OF THE PHAN:' WRITE(3,78) (RS(I),I=1,M)

78 FORMAT(/6X,9F12.5) WRITE(3,*)

DO 9 I=1,M

DO 8 J=1,M IJ=(I-1)*M+J

8 A(IJ)=XX0(I,J)

9 B(I)=XY0(I)

CALL SIMQ(A,B,M,KS) IF(KS.EQ.1) GOTO 99 SUM=0.

DO 10 J=1,M

10 SUM=SUM+B(J)*RS(J) R=SQRT(SUM)

WRITE(3,*)' HE SO VIEW BOI:' R1=SQRT(1.-(1-R*R)*(N-1)/(N-M+1))

WRITE(3,333) R1

333 FORMAT(/9X,'R1=',F8.5) WRITE(3,*)

WRITE(3,*)' COEFFICIENTS OF THE EQUATION WITH STANDARD VARIABLES

FLOWER:'

WRITE(3,11) (B(I),I=1,M)

11 FORMAT(/5X,9F14.6)

DO 12 J=1,M

12 BB(J)=B(J)*SY/SX(J) SUM=0.


DO 13 J=1,M

13 SUM=SUM+BB(J)*XTB(J) B0=YTB-SUM

WRITE(3,*)

WRITE(3,*)' THE COEFFICIENTS OF THE EQUATION WITH THE VARIABLE:' WRITE(3,14) B0,(BB(J),J=1,M)

14 FORMAT(/5X,F14.7,9F13.7)

DO 16 I=1,N SUM=0.

DO 15 J=1,M

15 SUM=SUM+BB(J)*X(I,J)

16 YTT(I)=B0+SUM WRITE(3,*)

WRITE(3,*) ' COMPARE REAL & REAL VALUES ' WRITE(3,*)

WRITE(3,*) ' STT Y(I) YTT(I) DEL(I) :' WRITE(3,*)

DO 17 I=1,N DEL(I)=Y(I)-YTT(I)

17 SS(I)=ABS(DEL(I))/Y(I)*100. SUM=0.

DO 18 I=1,N

18 SUM=SUM+SS(I) SSTB=SUM/N

WRITE(3,22) (I,Y(I),YTT(I),DEL(I),SS(I),I=1,N) 22 FORMAT(5X,I2,4F11.4)

WRITE(3,23) SSTB

23 FORMAT(//5X,'SSTB=',F6.3)

GOTO 999

99 WRITE(3,*)

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