Light Bulb Processing Technology Process at Viet Khai Company


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SPECIALIZED CONTAINER

ADDITIONAL ADDITIVES



SUPPORT FOR POWDER RECIPE

DUST


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Vapor Absorption Equipment

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THE MINUSONE AND THE AFFECTED

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DUST FILTER I

STORED IN 100L DRUM

VACUUM GRINDING

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COMMITTEE OF BUDGET


Figure 3.8. Light bulb processing technology process at Viet Khai Company


Technological process:

Used fluorescent lamps such as long tubes (1.2m; 0.6m), round bulbs, u-shaped bulbs (compact), monitor bulbs, etc. will be collected and stored in specialized containers. The containers are then transferred to the fluorescent lamp treatment equipment, which is a combination of the following equipment:

+ Crusher lid drive motor: The crusher lid drive motor has the function of moving (up or down) the crushing part.

+ Crusher: has the function of crushing light bulbs into powder with size from 0.5 - 10mm

+ Vacuum system: maintains vacuum pressure in the grinder, preventing mercury vapor and toxic chemicals from escaping into the surrounding air.

+ Dust filter system: has the task of filtering phosphorus dust and glass generated during the grinding process.

+ Mercury vapor adsorption system: mercury vapor in the bulb will be completely adsorbed into the adsorbents. First, mercury vapor will be adsorbed into activated carbon that has been activated with sulfur. Mercury vapor after being absorbed with activated carbon continues to be led through the aluminum powder container, then adsorbed once more with activated carbon after being released into the environment. Activated carbon that has been activated with sulfur and aluminum powder are substances with very high activity and have the ability to react well with mercury. The design of 2 times of mercury vapor adsorption with activated carbon between 1 time of adsorption with aluminum powder ensures complete treatment efficiency as well as enhances safety during treatment.

The powder mixture after grinding includes the metal part of the lamp base, filament, glass powder mixed with fluorescent powder and a very small amount of mercury mixed with fluorescent powder will be stored in a specialized 200 liter container, then this mixture will be concreted at the company's solidification system and safely buried according to the law. Each 200L container can hold from 1200 - 1300 crushed 1.2 m fluorescent lamps.

The mixture of dust and mercury-saturated adsorbent will also be periodically separated and stored in special 100L containers and also sent to hazardous waste treatment sites. Each of these 100L containers can contain the waste mixture from the treatment of 15,000 - 18,000 used fluorescent lamps 1.2m long.

3.2.3.8. Some other facilities send out survey forms to collect information.

The facilities with serial numbers from 8 to 13 in Table 3.2 basically have similar light bulb treatment technology to the technologies of the facilities described in detail above, so these facilities are only described in summary form.

3.2.4. Evaluation of advantages and disadvantages of currently applied waste light bulb treatment technologies

Through collected information, light bulb processing technologies belong to the following 3 basic groups:

- Group 1: Light bulb treatment technology using sulfur powder to absorb mercury vapor like the treatment technology of Tan Thuan Phong Company Limited;

- Group 2: Wet light bulb treatment technology, using activated carbon to adsorb mercury vapor such as: Green Industrial Environment Company Limited; Hoa Binh Industrial Waste Treatment and Recycling Joint Stock Company; Green Environment Production, Service and Trading Company Limited;

- Group 3: Dry light bulb treatment technology, using activated carbon to adsorb mercury vapor such as: Lilama Mechanical - Electrical - Environmental Joint Stock Company; Thanh Tung 2 Company Limited; Sao Viet Environmental Joint Stock Company; Thuan Thanh Environmental Joint Stock Company; Ho Chi Minh City Urban Environmental Company Limited; Viet Khai Environmental Treatment Service Trading Company Limited; Hung Hung Green Environment Company Limited; Water Supply and Drainage Company Limited

– Binh Duong Environment.

To assess the current status of light bulb treatment technology, the following will analyze the advantages and disadvantages of each type of technology:

Table 3.7. Comparison of current light bulb treatment technologies in Vietnam


Type

technology

Advantage

Disadvantages

Light bulb treatment technology uses sulfur powder to absorb mercury vapor

- The mercury vapor treatment process is periodically monitored by sampling and monitoring the exhaust gas after treatment.

- Because the device uses a washing process, the crushed glass does not contain fluorescent powder and can be recycled.

- Complex technology, many stages lead to high investment costs. Because of using water to wash glass, more wastewater is generated, leading to increased costs for treatment.

- Because of using sulfur powder, it is very difficult to adjust for the highest efficiency of mercury vapor absorption, and it is difficult to handle the mixture of residual sulfur powder and mercury.

sulfide because when solidifying must use

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Light Bulb Processing Technology Process at Viet Khai Company


Type

technology

Advantage

Disadvantages



Use acid-resistant cement but not regular cement for solidification.

leading to increased costs.

Wet bulb treatment technology using activated carbon to absorb mercury vapor

- Because the device uses a washing step, the resulting glass does not contain fluorescent powder and can be recycled.

- Because activated carbon is used to adsorb mercury vapor, it is easier to control the optimal operating mode than when using sulfur powder. After saturation, activated carbon is also easy to handle by solidification or landfill.

- Compact, easy-to-use processing equipment.

- The device operates intermittently so the processing capacity is not high. -

- Because the bulbs are loaded into the grinding chamber at the same time, it sometimes hinders the starting of the grinding unit (the grinding unit cannot start).

- Metal caps cannot be recovered because they are crushed together with the glass.

- The processing equipment has a complex structure, making maintenance and repair difficult.

- Because water is used for washing, in addition to the waste separated from the light bulbs, there is also wastewater generated from the washing process, which also increases costs.

processing

Dry light bulb processing technology

use activated carbon

- Using activated carbon to adsorb mercury vapor, so mercury vapor control is possible.

Effective evaluation.

Because there is no washing step, the glass after grinding still contains fluorescent powder.


Type

technology

Advantage

Disadvantages

mercury vapor adsorption

Because the separated waste has no purpose for recycling but is all solidified or buried, the dry light bulb treatment technology has an advantage. The separated waste is all dry so it is easy to solidify, and at the same time, no wastewater is generated, so the treatment cost is reduced.

- The device has a simpler structure and low technology investment costs.

- The device operates continuously so the processing capacity is high, the device operates stably and is easy to operate.

onion.


According to the above analysis of advantages and disadvantages, it shows that the technology of treating dry light bulbs using activated carbon to adsorb mercury vapor has more advantages than the remaining treatment technologies, which is proven by the number of facilities that have invested in this treatment technology being more than the other two technologies.

However, dry treatment technology only stops at the pre-treatment level (separating into separate wastes to facilitate the next treatment steps), the generated waste has not been recycled to save resources and limit the impact on the environment.

Currently, the facilities only collect aluminum caps for recycling, however, due to small capacity, the collected metal is not much, so sometimes the facilities often

solidify or bury (because the aluminum cap is mixed in the glass container, to recover the aluminum cap, it must be filtered to recover, leading to low economic efficiency).

The capacity of the light bulb treatment equipment is usually very small, about 5-10 kg/h. However, with such a small capacity, most facilities do not use the full capacity of the equipment because the facilities do not want to collect and treat light bulbs for the following reasons:

- Because the light bulb treatment equipment is only a pre-treatment, the generated waste must be treated in the next steps such as solidification or landfill, leading to increased costs, while the cost collected from the waste source owner is low. According to the reflection of some light bulb collection and treatment facilities, on average, each kg of light bulb often has to compensate for a loss of 500 -

1,000 VND/kg.

- Waste is often treated by solidification method, which requires a storage area for solidified waste, which takes up space.

- The source of discarded light bulbs is not concentrated, the quantity is small, leading to difficulties in collection, transportation and treatment. According to interviews and reports on hazardous waste data of some facilities, the amount of light bulbs generated from waste sources is about 1-2 kg/month on average.

3.2.5. Evaluation of the effectiveness of currently applied light bulb treatment technologies

According to the above analysis, the licensed light bulb treatment technologies are only at the pre-treatment level to separate into separate wastes (glass, metal caps, fluorescent powder and mercury after adsorption or absorption) to facilitate the next treatment steps, glass is not recovered for recycling, nor is there an effective solution to treat mercury after adsorption. Therefore, the efficiency is low both economically and environmentally. These treatment technologies are only temporary solutions at the present stage because there is no facility investing in a specialized light bulb treatment and recycling system to fully recover and recycle light bulbs.

The separated waste is further treated by solidification or landfill, when this waste still has the potential to pollute the environment and requires a lot of storage space.

In recent times, in order to provide a solution to thoroughly treat waste light bulbs, some facilities have proposed technologies including recycling glass, metal caps and desorption of mercury adsorbents to recover mercury, reuse the adsorbents in the process of evaluating environmental impact assessment reports and have been approved. However, in reality, because the current treatment equipment has a small capacity (5-10 kg/h), the recovery efficiency is not high.

Therefore, in order to improve the efficiency of recovery and recycling from the light bulb treatment process, in the coming time, it is necessary to conduct research to develop a treatment technology suitable for Vietnam's conditions in the direction of a centralized treatment model and reuse of glass tubes (whole tubes), only then can we minimize the impact on the environment and improve treatment efficiency.

3.3. Market for recycling and treatment of hazardous waste including discarded light bulbs in Vietnam

3.3.1. Current status of the market for recycling and processing discarded light bulbs

Currently, it can be said that the market for recycling and treating hazardous waste, including discarded light bulbs, in Vietnam is not yet developed. The total processing capacity of hazardous waste management practitioners only meets a part of the amount of hazardous waste generated. Some units still lack understanding or have not updated regulations on specialized hazardous waste transportation vehicles and types of waste treatment technologies at home and abroad, making it difficult to choose appropriate technology to install at the treatment facility. In addition, these practitioners do not have complete technical instructions related to specialized means and equipment for the practice of transporting and treating hazardous waste. At the same time, although the technical regulations/standards related to the practice of transporting and treating hazardous waste have been issued, they are still lacking and incomplete.

Regarding light bulb waste, the source of waste generated from industry is small, in small quantities, and not concentrated. According to statistics, on average, each facility generates about 1-2 kg of fluorescent light bulb waste per month; while the source generated from daily life is collected together with other waste, so it is difficult to arrange.

storage, collection, transportation and treatment areas, leading to high service costs and reducing the competitiveness of businesses. Therefore, in order to reduce service costs, some collection and treatment facilities do not comply with regulations. In addition, due to the small number of discarded fluorescent lamps, it is also an obstacle for businesses operating in the field of hazardous waste management to research and invest in equipment with advanced technology to process and recycle discarded lamps.

3.3.2. Research capacity, technology transfer and equipment manufacturing in waste recycling activities in Vietnam

Currently in Vietnam, a system of units operating in the field of waste recycling has been formed, including the following areas:

Pure research units: conduct research and develop recycling technologies on a laboratory scale, then replicate them on a real scale. For example, institutes, research centers, universities, and laboratories. Typical examples of these units include:

Institute of Environmental Science and Technology, Hanoi University of Science and Technology with research on improving recycling technology of craft villages, or initial research on recycling technology of electronic waste.

Institute of Environmental Science and Technology, Hanoi University of Civil Engineering with research on recycling household waste or incineration of waste to recover heat.

Institute of Construction Physics under the Ministry of Construction, researches technology to recycle waste PRT plastic into unsaturated polyester plastic to manufacture composite materials, Institute of Chemical Technology and Institute of Environmental Technology under the Vietnam Academy of Science and Technology.

Center for Environmental Technology and Sustainable Development.

Faculty of Chemistry, University of Science, Vietnam National University, Hanoi and many other units.

Units that combine research and manufacturing, installation and operation of recycling lines, such as the Environmental Equipment Manufacturing Mechanical Factory of the Hydraulic Machinery Company, Tran Vu Mechanical Private Enterprise, and Vietnam Environment Joint Stock Company.

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